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The pyroelectric effect

Ancient effect harnessed to produce electricity from waste heat


By American Chemical Society ——--June 27, 2012

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WASHINGTON, — The latest episode in the American Chemical Society’s (ACS’) award-winning Global Challenges/Chemistry Solutions podcast series describes the world’s first “electrified snail,” which now joins the menagerie of cockroaches, rats, rabbits and other animals previously implanted with biofuel cells that generate electricity — perhaps for future spy cameras, eavesdropping microphones and other electronics — from natural sugar in their bodies.
Based on a report by Zhong Lin Wang, Ph.D., and colleagues in the ACS journal Nano Letters, the new podcast is available without charge at iTunes and from www.acs.org/globalchallenges. In the report, Wang and colleagues explain that more than 50 percent of the energy generated in the U.S. every year goes to waste, much of it as heat released to the environment by everything from computers to cars to long-distance electric transmission lines. Heat can be converted to electricity using something called the pyroelectric effect, first described by the Greek philosopher Theophrastus in 314 B.C., when he noticed that the gemstone tourmaline produced static electricity and attracted bits of straw when heated. Heating and cooling rearrange the molecular structure of certain materials, including tourmaline, and create an imbalance of electrons that generates an electric current. Wang’s group wanted to apply the ancient principle to make a nanogenerator (NG), which uses a time-dependent temperature change to generate electricity and could take advantage of heat changes in the modern world.

To do that, the researchers made nanowires out of zinc oxide, a compound added to paints, plastics, electronics and even food. Using an array of short lengths of nanowire standing on end, they demonstrated a device that produces electricity when heated or cooled. They suggest the NGs could even produce power as temperatures fluctuate from day to night. “This new type of NG can be the basis for self-powered nanotechnology that harvests thermal energy from the time-dependent temperature fluctuation in our environment for applications such as wireless sensors, temperature imaging, medical diagnostics and personal microelectronics,” the researchers said. Global Challenges/Chemistry Solutions is a series of podcasts describing some of the 21st century’s most daunting problems, and how cutting-edge research in chemistry matters in the quest for solutions. Global Challenges is the centerpiece in an alliance on sustainability between ACS and the Royal Society of Chemistry. Global Challenges is a sweeping panorama of global challenges that includes dilemmas such as providing a hungry, thirsty world with ample supplies of safe food and clean water; developing alternatives to petroleum to fuel society; preserving the environment and assuring a sustainable future for our children and improving human health.

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American Chemical Society——

American Chemical Society, ACS is a congressionally chartered independent membership organization which represents professionals at all degree levels and in all fields of chemistry and sciences that involve chemistry.


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