Chemical weapons are nightmarish. In a millisecond, they can kill hundreds, if not thousands. But, in a study published in the ACS journal Chemistry of Materials, scientists report that they have developed a way to adhere a lightweight coating onto fabrics that is capable of neutralizing a subclass of these toxins — those that are delivered through the skin. The life-saving technique could eventually be used to protect soldiers and emergency responders.
Since their first use in World War I, dozens of chemical weapons with devastating potential have been developed. For example, just a pinprick-sized droplet of the nerve gas sarin on the skin is lethal. Recently, scientists have begun exploring the use of zirconium-based metal-organic framework (MOF) powders to degrade and destroy these harmful compounds. MOFs are miniscule, porous structures that have large surface areas that allow them to absorb vast amounts of gases and other substances. The zirconium within them helps neutralize toxic materials. But making MOFs can be tedious, requiring high temperatures and long reaction times. Plus, most MOF powders are unstable and incorporating them onto clothing has proven challenging. Dennis Lee, Gregory N. Parsons and colleagues wanted to see if they could "grow" MOFs onto fabric at room temperature, potentially creating a lightweight shield that could be used on uniforms and protective clothing.